Importance of geochemical transformations in determining submarine groundwater discharge-derived trace metal and nutrient fluxes     

Aaron J. Beck  Yoko Tsukamoto  Antonio Tovar-Sanchez  Miguel Huerta-Diaz  Henry J. Bokuniewicz  Sergio A. Sañudo-Wilhelmy 《Applied Geochemistry》2007

Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO₃, PO₄, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO₄ and NO₃ (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 10²– 8.2 × 10³ μmol d⁻¹). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 10³ μmol d⁻¹ (inland, freshwater well) vs. 2.1 × 10⁵ μmol d⁻¹(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.  相似文献   

Sequence stratigraphy of Holocene incised-valley fills and coastal evolution in the Gulf of Cádiz (southern Spain)     

Dabrio  Cristino J.  Zazo  Cari  Lario  Javier  Goy  José Luis  Sierro  Francisco J.  Borja  Francisco  González  José Ángel  Flores  José Abel 《Geologie en Mijnbouw》1998,77(3-4):263-281

This first sedimentary interpretation of two incised-valley fills in the Gulf of Cádiz (southern Spain), which accumulated during the last fourth-order eustatic cycle in response to fluvial incision, changes of sea level, and correlative deposition, relates the filling of the estuarine basins and their barriers with four regional progradation phases, H₁ to H₄. The cases studied are the wave-dominated Guadalete, and the mixed, tide and wave-dominated Odiel-Tinto estuaries. The sequence boundary is a type-1 surface produced during the lowstand of the Last Glacial period ca. 18 000 ¹⁴C yr BP. No fluvial lowstand deposits were found in the area. Due to rapid transgression the valley fills consist of transgressive and highstand sediments. The maximum landward advance of the estuarine barriers occurred ca. 6500–6000 ¹⁴C yr BP during the maximum of the Flandrian transgression, but there is no evidence of sea level rising appreciably above the present. A large part of the estuaries was filled during H₁ (ca. 6500–4400 ¹⁴C yr BP) but ravinement by shifting tidal inlets destroyed most of the coeval barriers. During the H₂ phase (ca. 4200–2550 ¹⁴C yr BP) sedimentation was favoured by arid conditions and concentrated in the axial estuarine zones and the barriers. Between H₂ and H₃ prevailing winds changed from W to WSW, increasing spit growth to the east and south-east. Progradation of bay-head deltas and flood-plains during H₃ (ca. 2300–800 ¹⁴C yr BP) and H₄ (500 yr ago to the present) further reduced the accommodation space in the largely-filled valleys, and sediment by-passed the estuaries and accumulated in the estuarine barriers as fast-growing spits. Arid conditions and increasing human activity have caused rapid coastal modifications.  相似文献   

A Method for Obtaining the Nuclear Component in Active Galaxies     

Miguel Sanchez Portal  Angeles I Diaz Beltran 《Astrophysics and Space Science》1998,263(1-4):119-122

We present a new method for the obtention of the nuclear component of active galatic nuclei, that relies on the convolution of a two-dimensional model of the host galaxy, based on seeing-free morphological parameters, with the seeing PSF. The procedure overcomes some limitations of the methods currently in use and does not assume that the nucleus is unresolved. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

CCD Surface Photometry of Nearby Active Galaxies     

M. Sánchez Portal  A.I. Diaz  M. Álvarez Álvarez  Roberto Terlevich  Elena Terlevich  Itziar Aretxaga 《Astrophysics and Space Science》1998,263(1-4):107-110

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Model for simulating soil-water content considering evapotranspiration — Reply     

Abas Afshar  Miguel A. Marino 《Journal of Hydrology》1979,40(3-4):393-395

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Moderately volatile siderophiles in ordinary chondrites     

Ermanno R. Rambaldi  Miguel Cendales 《Earth and Planetary Science Letters》1979,44(3):397-408

The contents of the moderately volatile elements Ga, Ge, Cu and Sb in ordinary chondrites give us some clues with regard to the metal-silicate fractionation process. Their concentration in coexisting magnetic and non-magnetic portions of members of each ordinary chondrite group will be discussed. Germanium and Sb are mostly siderophilic, but Ga is strongly lithophilic in unequilibrated chondrites; its partition coefficient between magnetic and non-magnetic portions is positively correlated with petrologic type in L and LL chondrites, but not in H4–6 chondrites. From 25 to 50% of the total Cu is found in the non-magnetic fraction of chondrites, but there is no correlation between Cu content and petrologic type. The abundances of Ga, Cu and Sb (relative to Si) are constant in ordinary chondrites, independent of the amount of metal present, indicating that these elements were not in solid solution in the metal phase of chondrites when the metal-silicate fractionation process occurred. Germanium, which is the most volatile among the four elements analyzed, is more abundant in H than in L and LL chondrites, indicating that it was fractionated by this process. Nebular oxidation processes can be responsible for the behavior of Ga if this element was in oxidized form when loss of metal occurred, but cannot explain the results for Cu and Sb which are predicted to condense as metals and accrete mostly in metallic form. It is possible that Cu and Sb, upon condensation, did not form solid solutions with metallic Ni-Fe until after the separation of metal from silicates took place.  相似文献   

The development of folds in bedded chert and related rocks in the Malaguide Complex, southern Spain     

Miguel Orozco  Rafael Galvez 《Tectonophysics》1979,56(3-4)

Folds and folding mechanism in a chert sequence and related rocks of the Maláguide Complex (the uppermost tectonic unit of the Betic Zone) have been investigated. The geometric study shows that folds that developed in the chert sequence are usually angular in shape and asymmetric. Chevron and conjugate folds are common.Folding in bedded chert is explained in terms of a suggested model:

1. (1) Development of folds by kink and conjugate kinking.

2. (2) As the shortening increases, the interlimb angles decrease; in the kink folds this is caused by a reduction of the angle between the layers within the kink and the kink boundaries. There seems to be a relationship between this angle and the asymmetrical thinning-out in the limbs of many folds: the smaller is the angle between the kink boundary and the layers within the kink band, the larger is the reduction of the thickness in these layers.

Single limestone layers embedded in slate deform very probably by a buckling mechanism, implying tangential longitudinal strain and an additional flattening.  相似文献   

Crystal bending in metamorphic calcite,and its relations to associated twinning     

Francis J. Turner  Miguel Orozco 《Contributions to Mineralogy and Petrology》1976,57(1):83-97

This paper deals with the incidence and geometry of lattice bending in calcite of naturally strained marble and possible relations in time to associated {01¯12} twinning, as revealed by microscopic examination with a universal stage. Microscopic technique and graphic treatment of data with a view to identifying the relation in time of bending to twinning, and possible glide mechanisms involved in the bending process are reviewed as a basis for present and subsequent investigation of this general topic.In most instances development of surviving thin e twins postdates bending of the host crystal (such twins everywhere are rationally oriented). Rarely (in contrast with experimental experience) some thin twins are slightly irrational (L_e lamellae) and apparently developed in the final stages of bending. Thick twins (a few tens of microns wide) on the other hand rather commonly predate or are synchronous with bending.The geometry of bending (external rotation) — especially for rotation less than 25° —commonly is compatible with models (based on experimental experience) of simple translation in the strained domains. The commonest translation system so identified is on {10¯11}, with sense of shear, where recognizable, either negative or positive. Translation on {02¯21} is relatively rare. Unexpectedly there is rather strong but not conclusive evidence of translation on {0001} parallel to an a axis. This mechanism, hitherto never identified with certainty, is now here documented unequivocally in a crystal of calcite experimentally strained at 300° C, 5 kb.  相似文献   

Reconnaissance geochronology of basement rocks from the Amazonas and Maranhão Basins in Brazil     

Adam Kovach  Harold W. Fairbairn  Patrick M. Hurley  Miguel A.S. Basei  Umberto G. Cordani 《Precambrian Research》1976,3(5):471-480

Rb/Sr whole rock as well as K/Ar whole rock and mineral age determinations have been carried out on drill core samples obtained from the crystalline basement underlying the Amazonas and Maranhão Basins in Brazil. The data confirm the existence of an ancient basement under the Upper and Middle Amazonas Basin. The primary age of the granitic rocks is estimated at about 1560 Ma which correlates with recent age data obtained on granitic rocks on both sides of the Amazonas syneclise. In some areas the K/Ar ages show a decrease probably due to the effect of the Nickerie thermal episode described previously in the Guayana Shield.In the basement of the interconnected Lower Amazonas and Maranhão Basins Late Precambrian (Caririan) metamorphism and igneous activity seems to have been pervasive. The data allow the continuation of the Brazilian age province known in northeastern Brazil under the Maranhão Basin, linking this province to the Brasilia-Paraguay orogenic belt of similar age.  相似文献   

DISTRIBUTION OF DYNAMIC WATER LEVEL IN A SHALLOW LAKE     

ISTVÁN BOGÁRDI  LUCIEN DUCKSTEIN  CHESTER C. KISIEL 《水文科学杂志》2013,58(4):473-484

ABSTRACT

The shore of a large and shallow reservoir or lake may incur damages caused by high or low static water level, as well as from dynamic water level rises induced by wind; thus, the random variables representing, respectively, static water level and wind-induced rise must be added. The case study of Lake Balaton, Hungary, illustrates a proposed methodology to estimate, on the one hand, the distribution function of monthly static water level and on the other hand, that of monthly maximum rise caused by wind (seiche plus waves). We consider one section of lake shore which is homogeneous from the viewpoints of types of structure, dominant winds and corresponding values of fetch, so that a well-defined damage function can be used later for that section. A convolution of the two distribution functions is performed to yield the distribution function of monthly maximum water level. On the basis of existing data, normal distributions are suggested for either static or dynamic water levels. Extensions and transferability of the methodology are discussed.  相似文献